范慧林,王宥宏,虞明香,张俊婷,王康康,刘忆恩,马琳,张鹏,赵嘉,胡鹏程.纳米硅合金负极材料[J].稀有金属材料与工程,2019,48(9):2899~2904.[FAN Hui-lin,WANG You-hong,YU Ming-xiang,ZHANG Jun-ting,WANG Kang-kang,LIU Yi-en,MA Lin,ZHANG Peng,ZHAO Jia,HU Peng-cheng.Nano-silicon alloy anode material[J].Rare Metal Materials and Engineering,2019,48(9):2899~2904.]
纳米硅合金负极材料
投稿时间:2018-04-17??修订日期:2018-05-30
中文关键词:??锂离子电池??纳米材料??负极材料??铜铝硅合金
基金项目:山西省重点研发计划重点项目(201603D112002)
中文摘要:
??????本文研究了一种纳米硅合金锂离子电池负极材料的微观组织和电化学性能。研究结果表明:该负极颗粒的轮廓基本呈圆形,其内部存在着两个含硅量不同的富铜相,在颗粒表层中两相均为纳米结构。该纳米硅合金负极材料需与石墨负极材料、粘结剂和导电剂按一定比例配合使用,搅拌工艺对其电化学性能也有重要影响。在较理想的情况下,所得负极材料的首效率提高到了90%上下,比容量在100周之后仍高于500mAh/g。电池制作工艺与石墨负极相似,便于应用。
Nano-silicon alloy anode material
英文关键词:Lithium-ion battery??nanomaterial??anode material??copper-aluminum-silicon alloy
英文摘要:
??????The microstructure and electrochemical property of nano-silicon alloy anode material are studied in this paper. The research shows that the outline of the nano-silicon particle is basically circular, and two copper-rich phases with different silicon contents are detected in the particle, and both phases with nanostructure are observed in its surface layer. The nano-silicon alloy negative electrode material needs to be used in a certain proportion with graphite, binder and conductive agent, and the stirring process also has an important influence on its electrochemical performance. The first-cycle coulombic efficiency of the material is improved to about 90%, and the specific capacity is still higher than 500 mAh/g after 100 cycles. The battery manufacturing process is similar to the graphite negative electrode, so it is easy to be applyed.
作者单位E-mail
范慧林?太原科技大学材料科学与工程学院?1397610672@qq.com?
王宥宏?太原科技大学?hlkdyx@sina.com?
虞明香?太原科技大学??
张俊婷?太原科技大学??
王康康?太原科技大学??
刘忆恩?山西沃特海默新材料科技股份有限公司??
马琳?山西沃特海默新材料科技股份有限公司??
张鹏?山西沃特海默新材料科技股份有限公司??
赵嘉?山西沃特海默新材料科技股份有限公司??
胡鹏程?山西沃特海默新材料科技股份有限公司??
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